Intrinsic Semiconductor

An intrinsic semiconductor is a type of semiconductor material that has a perfectly balanced number of electrons and holes at absolute zero temperature (0 Kelvin or -273.15°C). This means that its electrical conductivity is neither dominated by electrons (as in metals) nor holes (as in p-type semiconductors) but rather depends on the thermal generation and recombination of electron-hole pairs.

Intrinsic semiconductors are typically composed of Group IV elements in the periodic table, such as silicon (Si) or germanium (Ge). These materials have four valence electrons, which are shared covalently between neighboring atoms in a crystalline lattice structure.

intrinsic semiconductor

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Intrinsic semiconductors are a fundamental component of modern electronics, and understanding their atomic structure is key to comprehending their behavior. These materials, such as silicon (Si) and germanium (Ge), have a unique atomic arrangement that gives rise to their distinctive electrical properties.

At the heart of intrinsic semiconductors are silicon or germanium atoms. These atoms have four valence electrons in their outermost energy level. Valence electrons are crucial because they participate in electrical conductivity. Each silicon or germanium atom forms four covalent bonds with neighboring atoms by sharing electrons. This covalent bonding creates a crystalline lattice structure, where atoms are arranged in a repetitive three-dimensional pattern.

The crystalline lattice of intrinsic semiconductors is stable at low temperatures, and each atom is bonded tightly in place. However, at higher temperatures, some valence electrons can gain enough energy to break free from their covalent bonds, creating electron-hole pairs. This process is known as thermal excitation.


When an electron is excited to a higher energy state, it leaves behind an electron deficiency, or “hole,” in its original position. These holes can also carry an electrical charge and are considered positive charges moving through the crystal lattice.

Intrinsic semiconductors have an equal number of electrons and holes under equilibrium conditions, making them electrically neutral as a whole. However, they exhibit unique behavior when exposed to external influences like heat or light. For instance, when intrinsic semiconductors are exposed to light, photons can provide the energy needed to generate additional electron-hole pairs, enhancing their electrical conductivity.

The atomic structure of intrinsic semiconductors, with its covalently bonded lattice and the ability to create electron-hole pairs, forms the foundation of semiconductor device technology. By introducing controlled impurities, known as doping, into these materials, engineers can tailor their electrical properties for various applications, ranging from transistors and diodes in electronics to solar cells and sensors. This fundamental understanding of atomic structure is what underpins the remarkable versatility and utility of intrinsic semiconductors in our modern world.

Electron-Hole Pair Generation

Electron-hole pair generation is a fundamental process in semiconductors, driven by the absorption of energy (usually from light). It leads to the creation of mobile charge carriers (electrons and holes) that can conduct electricity, making it a cornerstone of modern electronics and energy conversion technologies like solar cells.

At absolute zero temperature, no electrons have enough thermal energy to break free from their covalent bonds and become charge carriers. However, as temperature increases, some electrons acquire sufficient energy to move into the conduction band, leaving behind positively charged holes in the valence band. This process is known as electron-hole pair generation.

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Electron-hole pair generation is a fundamental process in semiconductor physics and plays a crucial role in various electronic devices like solar cells and transistors.

Electron-hole pair generation is a fundamental process in semiconductor physics and plays a crucial role in various electronic devices like solar cells and transistors.

Imagine you have a piece of semiconductor material, like silicon, which is widely used in electronic devices. At the atomic level, silicon is made up of a lattice of atoms, each with electrons orbiting around its nucleus. These electrons are responsible for conducting electrical current in the material.

Now, let’s introduce some energy into this semiconductor. This energy can come from various sources, like light or heat. For the sake of simplicity, let’s consider light. When a photon of light, which carries energy, strikes the semiconductor, it can interact with an electron in the material.

When a photon with enough energy hits an electron, it can give that electron a boost, providing it with sufficient energy to break free from its current position within an atom. This process is known as “photoexcitation” or “photon absorption.”

When this happens, the electron leaves behind an empty space called a “hole” in its original position within the atomic lattice. This hole represents a positive charge because it’s missing an electron, which is negatively charged. So, we have an electron, which is negatively charged, moving freely in the material, and a hole, which is positively charged, left behind.


Here’s where the magic of electronics and semiconductor devices comes into play. Electrons and holes are attracted to each other due to their opposite charges. So, they start moving towards each other. Electrons move in one direction, while holes move in the opposite direction. This movement of charge carriers creates an electrical current within the semiconductor material.

This process of creating electron-hole pairs and allowing them to move freely through the material is the basis of how semiconductors conduct electricity. In the context of a solar cell, for example, this electron-hole pair generation is essential. When sunlight (composed of photons) strikes the solar cell, it generates electron-hole pairs, which then contribute to the flow of electricity and generate power.

Energy Band of Intrinsic Semiconductor

In an intrinsic semiconductor, there are two important energy bands. soch as,

  1. Valence band.
  2. Conduction band.

The valence band is filled with electrons, and the conduction band is empty at absolute zero. As temperature rises, the energy gap (Eg) between the valence and conduction bands determines the probability of electron-hole pair generation.

Valence bond – Picture this as the lower energy zone, where electrons hang out most of the time. They’re like people sitting in the front row at a movie theater – they’re content and don’t want to move. Electrons in the valence band are tightly bound to their atoms.

Conduction Band: Now, let’s zoom up a level. The conduction band is like the balcony seats in our movie theater analogy. Electrons here have more energy, and they’re free to move around the crystal lattice. They’re like the audience members who can jump from one seat to another.

Imagine an intrinsic semiconductor as a quiet, pure crystal with its atoms perfectly aligned. It’s like a calm pond on a windless day. In this serene setting, the electrons have distinct energy levels where they’re comfortable.

The gap between these two bands is what we call the “bandgap.” It’s like the space between the front row and the balcony, and it’s crucial in understanding the behavior of semiconductors.

In an intrinsic semiconductor, this bandgap is significant, which means electrons in the valence band need a substantial boost of energy to jump up to the conduction band. But it’s not always easy for them to get that boost. They can gain energy from various sources like heat or light, but under normal conditions, they prefer to stay put.

However, this bandgap is precisely what makes intrinsic semiconductors interesting. When we apply an external influence, like a voltage or light, we can give those valence band electrons just enough energy to jump to the conduction band. This creates what’s called an “electron-hole pair.”

These electron-hole pairs are like a pair of dance partners. The electron moves to the conduction band (the balcony), leaving behind a “hole” in the valence band (the front row). These “holes” can also move around, effectively behaving like positive charges.

Now, engineers and scientists can manipulate these electron-hole pairs in semiconductors to make electronic devices like diodes and transistors. By controlling the flow of these pairs, we can create the logic and amplification that power modern electronics.

So, the energy bands in intrinsic semiconductors are like the theater seats for electrons, and the bandgap is the hurdle they need to jump. It’s this property that forms the foundation of semiconductor physics and the technology we rely on every day.

Intrinsic Carrier Concentration

At any given temperature, an intrinsic semiconductor will reach a state of dynamic equilibrium where the rate of electron-hole pair generation is equal to the rate of recombination. This equilibrium results in a specific concentration of free electrons (n) and holes (p), known as the intrinsic carrier concentration (ni).

The intrinsic carrier concentration (ni) increases exponentially with temperature according to the intrinsic carrier concentration equation:ni = A * T^3/2 * exp(-Eg / (2kT))Where:

  • A is a material-specific constant.
  • T is the absolute temperature (in Kelvin).
  • Eg is the energy bandgap of the semiconductor.
  • k is Boltzmann’s constant.

Electrical Conductivity

Intrinsic semiconductors have relatively low electrical conductivity at room temperature due to the small number of thermally generated electron-hole pairs. However, their conductivity can be significantly enhanced by introducing impurities, a process known as doping, which creates extrinsic (n-type or p-type) semiconductors.

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Electrical conductivity in intrinsic semiconductors is a fundamental property that characterizes their ability to conduct electric current. Intrinsic semiconductors are pure semiconductor materials, such as silicon (Si) or germanium (Ge), with no intentional doping or impurities.

Here are some key details about electrical conductivity in intrinsic semiconductors:

  1. Band Structure: In intrinsic semiconductors, the electronic band structure plays a crucial role in determining their electrical conductivity. These materials have a valence band filled with electrons and a conduction band separated by an energy bandgap (Eg). The bandgap is the minimum energy required to promote an electron from the valence band to the conduction band.
  2. Electron-Hole Pairs: At absolute zero temperature (0 K), intrinsic semiconductors have all their electrons in the valence band, and the conduction band is empty. However, as the temperature increases, some electrons gain enough thermal energy to move from the valence band to the conduction band, creating electron-hole pairs. An electron leaves behind a “hole” in the valence band, which behaves like a positively charged particle.
  3. Electrical Conductivity Mechanism: The electrical conductivity in intrinsic semiconductors arises primarily from the movement of these electron-hole pairs in response to an applied electric field. Electrons move toward the positive terminal, while holes move toward the negative terminal, resulting in the flow of current.
  4. Temperature Dependence: The electrical conductivity of intrinsic semiconductors strongly depends on temperature. As the temperature increases, more electrons acquire the energy to move to the conduction band, increasing the number of charge carriers and thus enhancing conductivity.
  5. Bandgap and Conductivity: The size of the energy bandgap (Eg) is a critical factor in determining the electrical conductivity of intrinsic semiconductors. A smaller bandgap allows electrons to more easily transition to the conduction band, leading to higher conductivity.
  6. Intrinsic Carrier Concentration: Intrinsic semiconductors have an intrinsic carrier concentration (ni), which represents the equilibrium concentration of electron-hole pairs at a specific temperature. The expression for ni depends on the material’s properties and the temperature.
  7. Practical Applications: Intrinsic semiconductors have limited use in practical electronic devices due to their low conductivity compared to doped (extrinsic) semiconductors. However, they serve as a foundation for understanding semiconductor behavior and are used as substrates for integrated circuits and other semiconductor devices.

Intrinsic semiconductors exhibit electrical conductivity due to the generation of electron-hole pairs at finite temperatures. Their conductivity depends on factors such as temperature, bandgap, and intrinsic carrier concentration, making them a fundamental component of semiconductor physics and technology.

Doped Semiconductors

Doped semiconductors play a crucial role in modern electronics. They’re like the secret sauce that gives semiconductors their incredible versatility.

Imagine a semiconductor as a pristine crystal lattice, where atoms are neatly arranged. Now, let’s “dope” it. Doping is like adding a pinch of seasoning to a dish – it changes everything.

Doping involves intentionally introducing impurities into the crystal lattice. These impurities are typically atoms of other elements. There are two main types: N-type and P-type.

  1. N-type Doping: Think of it as adding a dash of electrons. By introducing elements like phosphorus, we get extra electrons floating around in the lattice. These extra electrons make the material conductive, which is essential for things like transistors.
  2. P-type Doping: Now, let’s sprinkle in some “holes” by adding elements like boron. This creates gaps in the lattice structure, which act as if they were positively charged particles. These “holes” can accept electrons, making the material conductive in a different way.

Together, N-type and P-type regions create what’s known as a PN junction. This junction is the heart of devices like diodes and transistors, allowing precise control of electrical currents.

What’s amazing is that by carefully controlling the type and amount of doping, we can create a wide range of semiconductor devices, from microchips in your phone to solar panels and lasers. So, in essence, doping is the secret ingredient that makes semiconductors so incredibly versatile and essential in our technology-driven world.

Extrinsic vs Intrinsic

extrinsic vs Intrinsic semiconductor

Extrinsic and intrinsic are terms often used to describe different aspects of various concepts. Here’s a brief explanation of both:

  1. Extrinsic:
    • Extrinsic refers to something that originates from outside or is external to a particular object, system, or situation.
    • In the context of motivation or rewards, extrinsic motivation involves external incentives, such as money, prizes, or recognition, that drive a person to perform a task or achieve a goal.
  2. Intrinsic:
    • Intrinsic means something that comes from within or is inherent to a specific object, system, or situation.
    • Intrinsic motivation refers to the internal desire or satisfaction that a person derives from performing a task or engaging in an activity. It’s driven by personal interest, enjoyment, or a sense of fulfillment.

These terms can apply to various fields, including psychology, motivation, and properties of objects.

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Here are additional examples and contexts where the terms extrinsic and intrinsic are commonly used:


  1. Extrinsic Rewards: In the workplace, employees may receive extrinsic rewards such as bonuses, promotions, or raises for meeting specific performance targets.
  2. Extrinsic Factors in Sports: In sports, extrinsic factors like crowd support, financial incentives, or external pressures can influence an athlete’s performance.
  3. Extrinsic Value of Goods: When assessing the value of a product or service, factors like its market price, branding, and external demand contribute to its extrinsic value.
  4. Extrinsic Allergens: In the context of allergies, extrinsic allergens are substances from outside the body, like pollen or certain foods, that trigger allergic reactions.


  1. Intrinsic Motivation in Learning: In education, intrinsic motivation leads students to engage in learning because they find the subject interesting or personally fulfilling, rather than solely for external rewards or grades.
  2. Intrinsic Qualities of Materials: When discussing materials, intrinsic properties refer to characteristics like density, hardness, or melting point that are inherent to the material itself.
  3. Intrinsic Value of Nature: Environmental ethics often consider the intrinsic value of nature, asserting that ecosystems and species have inherent worth beyond their utility to humans.
  4. Intrinsic Characteristics of Personality: When describing a person’s character, intrinsic traits refer to their innate qualities, such as kindness or honesty.
  5. Intrinsic Beauty: In aesthetics, intrinsic beauty relates to the inherent qualities that make something beautiful, as opposed to superficial or externally imposed standards of beauty.

These concepts can be applied in various disciplines to analyze and understand the different aspects of objects, behaviors, and values.

Density of states in Intrinsic Semiconductor?

Density of states in Intrinsic Semiconductor?

The density of states in an intrinsic semiconductor describes the distribution of energy states available to electrons and holes without the influence of impurities or external doping. It typically follows a parabolic relationship and can be described by the effective mass approximation. In three dimensions, the density of states (DOS) for electrons can be expressed as:

D(E) = 2 * (2πm* / h^2)^(3/2) * √E


  • D(E) is the density of states per unit volume per unit energy.
  • m* is the effective mass of the charge carriers (usually electron effective mass for electrons).
  • h is the Planck constant.
  • E is the energy.

For holes, it’s a similar expression:

D_h(E) = 2 * (2πm_h* / h^2)^(3/2) * √E

where m_h* is the effective mass of holes.

This expression gives you the density of states at a specific energy level E in an intrinsic semiconductor. Keep in mind that these equations are simplifications and that more detailed models exist for specific semiconductor materials that take into account their specific band structures and effective masses.


Intrinsic semiconductors serve as the foundation for various electronic devices. They are used as the base material in the fabrication of transistors, diodes, and integrated circuits. By controlling the doping process, engineers can tailor the electrical properties of semiconductors to suit specific applications in the electronics industry.


Intrinsic semiconductors are pure semiconductor materials with a balanced number of electrons and holes at absolute zero temperature. Their electrical properties are fundamentally temperature-dependent, and they form the basis for the development of advanced electronic devices and integrated circuits.


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